Magnetic nanoparticles can boost the performance of solar cells made from polymers – provided the mix is right, a new study has found. Adding about one per cent of such nanoparticles makes the solar cells more efficient, according to a team of scientists in Germany.
Polymer, or organic, solar cells offer tremendous potential: They are inexpensive, flexible and extremely versatile. Their drawback compared with established silicon solar cells is their lower efficiency. Typically, they only convert a few per cent of the incoming light into electrical power. Nevertheless, organic solar cells are already economically viable in many situations, and scientists are looking for new ways to increase their efficiency.
One promising method is the addition of nanoparticles. It has been shown, for example, that gold nanoparticles absorb additional sunlight, which in turn produces additional electrical charge carriers when the energy is released again by the gold particles.
A research team at Technische Universität München (TUM) has been pursuing a different approach. “The light creates pairs of charge carriers in the solar cell, consisting of a negatively charged electron and a positively charged hole, which is a site where an electron is missing,” explains Daniel Moseguí González, the lead author of a new study published in the journal Advanced Energy Materials.
“The art of making an organic solar cell is to separate this electron-hole pair before they can recombine. If they did, the charge produced would be lost. We were looking for ways of extending the life of the electron-hole pair, which would allow us to separate more of them and direct them to opposite electrodes,” says Moseguí González.
Magnetite nanoparticles increase efficiency
This strategy makes use of a quantum physical principle which states that electrons have a kind of internal rotation, known as spin. According to the laws of quantum physics, this spin has a value of 1/2. The positively charged hole also has a spin of 1/2. The two spins can either add up, if they are in the same direction, or cancel each other out if they are in opposite directions. The electron-hole pair can therefore have an overall spin of 0 or 1. Pairs with a spin of 1 exist for longer than those with an overall spin of 0.
The researchers set out to find a material that was able to convert the spin 0 state into a spin 1 state. This required nanoparticles of heavy elements, which flip the spin of the electron or the hole so that the spins of the two particles are aligned in the same direction. A mineral called magnetite – an iron oxide – is able to do just this.
“In our experiment, adding magnetite nanoparticles to the substrate increased the efficiency of the solar cells by up to 11 per cent,” reports Moseguí González. The lifetime of the electron-hole pair is significantly prolonged.
X-ray investigation reveals optimal nanoparticle levels
Adding nanoparticles is a routine procedure that can easily be added to the various methods for manufacturing organic solar cells. But it’s important not to add too many nanoparticles to the solar cell, because the internal structure of organic solar cells is finely adjusted to optimise the distance between the light-collecting, active materials. That way, the pairs of charge carriers can be separated as efficiently as possible. These structures lie in the range of 10 to 100 nanometres.
How long is a nanometre?
Not very long at all… To put things in perspective: a strand of your DNA is about 2.5 nanometres in diameter; a strand of your hair is 50,000 to 100,000 nanometres thick.
“The X-ray investigation shows that if you mix a large number of nanoparticles into the material used to make the solar cell, you change its structure”, explains study co-author Stephan Roth.
Roth was in charge of experiments conducted using the X-ray source PETRA III at the German X-ray synchrotron DESY – a research facility housing very powerful particle accelerators for studying the structure of matter.
“The solar cell we looked at will tolerate magnetite nanoparticle doping levels of up to one per cent by mass without changing their structure,” says Roth.
The scientists observed the largest effect when they doped the substrate with 0.6 per cent nanoparticles by weight. This caused the efficiency of the polymer solar cell examined to increase from 3.05 to 3.37 per cent.
“An 11 percent increase in energy yield can be crucial in making a material economically viable for a particular application,” says Peter Müller-Buschbaum, who led the team.
The researchers believe it will also be possible to increase the efficiency of other polymer solar cells by doping them with nanoparticles. “The combination of high-performance polymers with nanoparticles holds the promise of further increases in the efficiency of organic solar cells in the future. However, without a detailed examination, such as that using the X-rays emitted by a synchrotron, it would be impossible to gain a fundamental understanding of the underlying processes involved,” concludes Müller-Buschbaum.
Adapted from article by Andreas Battenberg, TUM Research News